Step 1. Create a new document 5x5x300dpi
Step 6.Click on the top layer in your layers palette. Then click on "Edit" in the top menu Drop down to "Stroke"
Step 7.choose 1 pixel, Black, stroke inside (if you want bolder outlines you can choose more pixels for a broader outline)
Step 17.For the tiny places use a brush tool in a small size (see diagram)
Step 23.working on the top layer, drag a rectangle around your letter; stroke with the width and color of your choice
Step 25.You can continue with a band of different colored outlines by changing colors in your tool box and choosing "Stroke" in various widths.
Step 26.This letter is outlined in gold, teal and black. You can stop here or fill in your box with a different background color.
Step 27.choose a color for the background; select the paint bucket tool; be sure you are working on the layer with the stroked rectangle; click in the interior space to fill it in